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14:09
YouTube
CrashCourse
Cyclohexanes: Crash Course Organic Chemistry #7
Hexagons appear all over the natural world from honeycomb to bubbles, and they even appear in organic chemistry! In this episode of Crash Course Organic Chemistry, we're learning all about cyclohexanes, including how rings pucker to relieve strain, the boat and chair conformations, and how ring flips can switch substituents from axial to ...
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Jul 8, 2020
Cyclohexanone Synthesis
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23-64 The Stork enamine reaction and the intramolecular aldol reaction canbe carried out in sequence to allow the synthesis of cyclohexenones.For example, reaction of the pyrrolidine enamine of cyclohexanonewith 3-buten-2-one, followed by enamine hydrolysis and base treat-ment, yields the product indicated. Write each step, and show themechanism of each.
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SOLVED: The ketone IR frequencies of cyclohexanone and cyclohex-2-enone are indicated below: Use resonance structures to help explain why the IR frequency in cyclohex-2-enone is lower than cyclohexanone.CyclohexanoneCyclohex-2-enoneAlcohols, carboxylic acids, and water exhibit a very broad O-H peak between 3200 and 2600 cm-1. Broad peaks are typically associated with intermolecular interactions resulting in multiple bonding scenarios. What intermolecular interactions between the molecules of the
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