An improved catalytic system was developed for the Rh complex-catalyzed hydroxycarbonylation of alkenes using formic acid (HCOOH). Ligand screening revealed DPEphos, a bidentate phosphine ligand, to ...

Three Rh−phosphinite complexes with the general structural formula [RhCl(i-Pr2POXy)(L)]2 (Xy = 2,3-xylyl; L = PPh3, PMe3, t-BuNC) were synthesized. Characterization of these complexes using ...

G. A. Crosby and W. H. Elfring Jr. Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These ...

Direct oxidation of methane into value-added liquid chemicals is a promising route for wide applications. However, the efficient conversion of methane with high selectivity under mild conditions is ...

An efficient rhodium-catalyzed asymmetric addition reaction of potassium alkenyltrifluoroborates to N-nosylaldimines has been developed. Under optimal conditions, the reactions proceeded with good to ...

An air-stable P-chiral bisoxaphospholane ligand (2S,2′S,3R,3′R)-BIOP is designed and developed. Ligand BIOP has shown high efficiency in rhodium-catalyzed asymmetric hydroformylation of various ...

Rhodium-catalyzed regioselective arylzincation of terminal allenes affords synthetically useful functionalized allylzinc reagents. The allylzinc reagents react with a variety of electrophiles such as ...

The experimental and computational data on rhodium binary alloys is sparse despite its importance in numerous applications, especially as an alloying agent in catalytic materials. Half of the ...

Heterotrimetallic Tetrathiomolybdato and Tetrathiotungstato Complexes of Rhodium(I) and Copper(I) with Rh-Mo(W)-Cu Interactions. ... Tomislav Pintauer, Partha Basu, William T. Eckenhoff. Structural ...

Rhodium(III)-catalyzed C–H activation-based arylation of sterically hindered (hetero)arenes has been realized using diazo compounds and triazoles as arylating reagents for atroposelective synthesis of ...

PAWTUCKET – Each bottle of Rhodium liquor tells a unique story of locality, environmentalism, love, and innovation. This women, veteran, LGBTQ, BIPOC, employee-owned nano-distillery goes above ...

A novel rhodium-catalyzed oxidative cyclocarbonylation of ketimines via cleavage of two C–H bonds was established, which provided a direct and reliable method for the synthesis of a wide range of ...